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Technology

Definition of AAO (Anodized Aluminium Oxide)


Anodizing is a type of metal surface treatment technology. 


Metal surface treatment refers to a technology that physically and chemically corrodes metals and non-metals or changes surface properties to improve the appearance, durability, and functionality of materials and parts without changing the characteristics of the raw materials. 

Anodizing refers to the process of electrochemically oxidizing a metal surface to form a nanoporous film with many holes, and using aluminum as the anode in an electrolyte and passing electricity through it is called aluminum anodization. 

In the process of aluminum anodization, the aluminum surface is oxidized by oxygen generated at the anode to form an aluminum oxide film, which is called 'anodized aluminum AAO (Anodized Aluminium Oxide)'. 


Large-Area AAO

Anodizing Technology 

Definition of AAO (Anodized Aluminium Oxide)

Anodizing is a type of metal surface treatment technology. 

Metal surface treatment refers to a technology that physically and chemically corrodes metals and non-metals or changes surface properties to improve the appearance, durability, and functionality of materials and parts without changing the characteristics of the raw materials. 

Anodizing refers to the process of electrochemically oxidizing a metal surface to form a nanoporous film with many holes, and using aluminum as the anode in an electrolyte and passing electricity through it is called aluminum anodization. 

In the process of aluminum anodization, the aluminum surface is oxidized by oxygen generated at the anode to form an aluminum oxide film, which is called 'anodized aluminum AAO (Anodized Aluminium Oxide)'. 


AAO has two types

well type with a barrier layer blocking the bottom and through-hole type including through holes. 


Characteristics of AAO

Technology > Large-Area AAO

Anodizing Technology 


※ Source : colloidal and polymer science,

25 sep 2020, volume 299, 325-341

toolbox of porous anodic aluminum

oxide–based nanocomposites : from

preparation to application




AAO is known to be able to control pore size, barrier thickness, and interpore distance by controlling applied voltage, temperature, purity of raw material aluminum, and anodizing process.

※ Source : Nanomaterials 2023, 13(21), 2853 Advances

in the Fabrication of Nanoporous Anodic Aluminum Oxide and Its Applications to Sensors : A Review


Problems with Manufacturing Methods and

Products of current technology 

Non-uniformity

After 1st Anodizing, the pores are not formed uniformly, so it is a generally known working method to remove them by etching and perform 2nd Anodizing, but even after 2nd Anodizing, the uniformity of the pore size is low. 

Instability

Due to the characteristics of metal oxides, they are easily broken and lack flexibility, making them difficult to handle, and in many cases, they cannot be applied in the application product development process. 

High Price 

Only one membrane is manufactured from one Al substrate, and since it is easily broken and difficult to handle, large-area manufacturing is difficult, so the selling price is very high. 

AAO has two types


well type with a barrier layer blocking the bottom and through-hole type including through holes. 


Characteristics of AAO


Technology > Large-Area AAO Anodizing Technology

※ Source : colloidal and polymer science, 25 sep 2020, volume 299, 325-341 toolbox of porous anodic aluminum oxide–based nanocomposites : from preparation to application
※ Source : colloidal and polymer science, 25 sep 2020, volume 299, 325-341 toolbox of porous anodic aluminum oxide–based nanocomposites : from preparation to application

AAO is known to be able to control pore size, barrier thickness, and interpore distance by controlling applied voltage, temperature, purity of raw material aluminum, and anodizing process. 

※ Source : Nanomaterials 2023, 13(21), 2853 Advances in the Fabrication of Nanoporous Anodic Aluminum Oxide and Its Applications to Sensors : A Review
※ Source : Nanomaterials 2023, 13(21), 2853 Advances in the Fabrication of Nanoporous Anodic Aluminum Oxide and Its Applications to Sensors : A Review

Problems with Manufacturing Methods and Products of current technology 

Non-uniformity

After 1st Anodizing, the pores are not formed uniformly, so it is a generally known working method to remove them by etching and perform 2nd Anodizing, but even after 2nd Anodizing, the uniformity of the pore size is low. 

Instability

Due to the characteristics of metal oxides, they are easily broken and lack flexibility, making them difficult to handle, and in many cases, they cannot be applied in the application product development process. 

High Price 

Only one membrane is manufactured from one Al substrate, and since it is easily broken and difficult to handle, large-area manufacturing is difficult, so the selling price is very high. 

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Hexapro's AAO 

Secured large-area AAO manufacturing technology and at the same time

possesses AAO manufacturing technology that is unbreakable and flexible 


Hexapro's AAO 

Secured large-area AAO manufacturing technology and at the same time possesses AAO manufacturing technology that is unbreakable and flexible 

Physical Properties of Hexapro’s AAO


AAO manufactured by Hexapro's method is large-area and has good pore uniformity. 

Hexapro AAO pore uniformity is very high compared to competitors' products. 

Physical Properties of Hexapro’s AAO

AAO manufactured by Hexapro's method is amorphous.

AAO manufactured by Hexapro's manufacturing method has many pores and low dielectric constant. 

Large-Area AAO

Anodizing Technology 

Physical Properties of Hexapro’s AAO 


AAO manufactured by Hexapro's method is large-area and has good pore uniformity. 


Hexapro AAO pore uniformity is very high compared to competitors' products. 

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Physical Properties of Hexapro’s AAO 

AAO manufactured by Hexapro's method is amorphous.

Large-Area AAO

Anodizing Technology 

Dielectric Constant Dielectric Loss 
Other Companies Hexapro AAOOther Companies Hexapro AAO

Al2O3

powder

AAO Membrane
(Al 95%)
AAO Membrane
(Al 99.999%)

AAO powder

(Al 99.5%)

Al2O3

powder

AAO Membrane
(Al 95%)
AAO Membrane
(Al 99.999%)

AAO powder

(Al 99.5%)

7.5692.2041.8452.0050.0020.0050.0130.015
7.925
2.2251.8452.0160.0060.0030.0180.021
8.3452.2321.8332.0230.0090.0050.0140.020
8.8232.1851.8321.9980.0190.0060.0200.030
8.7102.2011.7852.0260.0180.0190.0340.038

Secured technology to apply constant voltage and current to large-area aluminum during the anodizing process for large-area AAO manufacturing.

Secured mass production technology for sizes of 20cm x 20cm and larger Bench-scale technology secured 


Existing technology: Large-area manufacturing impossible Hexapro technology: Large-area manufacturing technology secured

(Left - Failure)

With existing methods, there's an issue where the entire aluminum surface does not get anodized uniformly. 


(Right - Success)

Hexapro has secured the technology to anodize an entire 20 x 20cm aluminum surface uniformly without damage.



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